Nitrosoamine free preservative system for natural rubber latex

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dc.contributor.authorUdayangani, G.G.D.
dc.contributor.authorNilmini, A.H.L.R.
dc.contributor.authorSirimanne, P.M.
dc.date.accessioned2022-03-22T10:11:22Z
dc.date.available2022-03-22T10:11:22Z
dc.date.issued2013
dc.description.abstractcolloidal dispersion of rubber particles in an aqueous medium, containing usually from about 20% to about 40% w/w rubber particles (dry rubber) and about 5% w/w non-rubber compounds, including carbohydrates, proteins, phospholipids and metal salts. Since it provides an optimum environment for microbial growth, in the absence of a proper preservation, the carbohydrates which the latex contains are oxidized in to short chain volatile fatty acids due to microbial activities. These acids destabilize the latex which results the coagulation of rubber particles (Blackley, 1997). Preservatives can effectively inhibit the bacterial growth in fresh NR latex. Hence the formation of acidic compounds resulting from bacterial activity in the latex is inhibited, which in turn inhibits coagulation. Since the most widely used preservative, Tetramethyl thiurumdisulfide (TMTD) forms carcinogenic nitrosamine, present invention is mainly focused on the provision of a nitrosoamine free preservative system for latex concentrate to stabilize the latex over a period of six months. Volatile fatty acid number is an important measure of the level of deterioration and stability of the latex. Therefore the preservative activities of new developing system (NDS) for treated latex concentrate was tested based on the measurements of volatile fatty acids (VFA) number test. The current study was carried out at the Rubber chemistry & Technology laboratories of Rubber Research Institute, Ratmalana. Three experimental trials with different treatments of NDS were conducted during this study. The trial (I) was carried out to find out the optimum concentration of NDS in preservation of natural rubber latex. In order to compare the efficiency of NDS with the conventional preservative, the VFA number of the latex, treated with ammonia/TMTD/ZnO (TZ) system and NDS was determined respectively. In trial (II), the effect of NDS on latex preservation in combination with a co-activator was determined. The effect of ammonia on the activity of novel preservative and the appropriate combination of ammonia and NDS to preserve and stabilize the latex were evaluated in trial (III).The appropriate combination was used to prepare centrifuged latex and other properties of the concentrated latex such as total solids content (TSC), dry rubber content (DRC), pH, KOH number, Brookfield viscosity were measured according to ISO standard methods and compared with the centrifuged latex preserved by adding 0.2% ammonia (NH 3), 0.025% of 1:1 mixture of tetramethylthiuramdisulphide (TMTD) and Zinc oxide (ZnO) combination as a control sample.VFA values of trial (I) and (II) were analyzed using one way analysis of variance (ANOVA) with MINITAB statistical package 16.0 version. The Experiment trials were done using complete randomized design (CRD). Means comparison of results was done by using the least significant difference (P<0.05) test (LSD).en_US
dc.identifier.urihttp://www.erepo.lib.uwu.ac.lk/bitstream/handle/123456789/8547/31-SCT-Nitrosoamine%20free%20preservative%20system%20for%20natural%20rubber%20latex%20.pdf?sequence=1&isAllowed=y
dc.language.isoenen_US
dc.publisherUva Wellassa University of Sri Lankaen_US
dc.subjectScience and Technologyen_US
dc.subjectTechnologyen_US
dc.subjectRubber Productionen_US
dc.subjectRubber Technologyen_US
dc.subjectNatural Rubberen_US
dc.subjectChemicalen_US
dc.titleNitrosoamine free preservative system for natural rubber latexen_US
dc.title.alternativeResearch Symposium 2013en_US
dc.typeOtheren_US
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