Browsing by Author "Weerawansha, A.N."
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Item Effect of graphite derivatives on mechanical and functional properties of nitrile rubber nano composite(Uva Wellassa University of Sri Lanka, 2015) Rajapaksha, P. C.; Alakolanga, A.G.A.W.; Weerawansha, A.N.; Rathnayake, U.N.The conducting polymers and polymeric composites have attracted considerable attention in recent years because of their breadth applications in advanced technologies, for example, in antistatic coatings, electromagnetic shielding. For all applications, elastomers are reinforced with fillers to promote their performance by incorporating materials such as silica, clay, carbon blacks, etc. Graphite is a layered material with high aspect ratio in its exfoliated state; it is also considered as one of the strongest materials per unit weight and has unique functional properties such as good electrical and thermal conductivities, and good lubricating properties. In other side graphene have recently received significant attention due to its outstanding electronic, mechanical and thermal properties. NBR-based Nano composite was prepared and mechanical and functional properties were studied. The dispersion of the filler in the polymer matrix was studied using the Transmitted light metrological microscope. Methodology Two different experimental trials (Preparation of NBR/Graphite composite and NBR/Graphene Nano composite) with different treatments (Phr levels) were conducted during this study. Nitrile rubber composites were prepared accordance with Brabender Plasticorder (Model: PL-2000; 26 manufacturers: ArtisanTM Technology Group).Item Optimization the physical properties of carbon black filled tread compound by replacement with silica(Uva Wellassa University of Sri Lanka, 2015) Perera, W.P.M.D.A.; Alakolanga, A.G.A.W.; Weerawansha, A.N.; Kularathna, S.In tire industry, carbon black (CB) is a widely used filler all over the world (Studebaker, 1965). Being a product made out of petroleum, there would be scarcity issue with the time, if continue to use in which it is being used today. It is a high time to look at feasibility of replacing CB with an alternative such as silica partially/fully as a solution for foreseen scarcity. Compared to CB, there won’t be scarcity as due to the fact it is made out of quartz (SiO2) which is readily available in earth crust. In this research, an attempt has been made to study the feasibility to go for possible replacement with silica while meeting the physical property requirement of a tread compound. Methodology The current study was carried out at Loadstar (Pvt) Ltd, Ekala. This study was conducted as two separate experiments. In experiment I, optimum CB/Silica combination which gives overall physical properties was evaluated. Five tread compounds were prepared. Each compound has the same ingredient except filler amount. Total filler amount was kept constant at 50 phr level. Carbon black and powder silica was varied in the ranged from 0 to 50 phr level to prepare the tread compounds with different CB/Silica ratios. Weight of all ingredients in the recipes was in units of per hundred rubbers. Batch weight was 1100 kg. Compound without silica was treated as the reference compound. The compounds were named as Si0, Si15, Si25, Si35 and Si50 to indicate the amount of silica incorporated in the compounds. Silane was added when incorporation of silica as 1 phr of Silane for 8 phr of silica as the coupling agent. Experiment II was carried out to find out the effective silica type in order to optimize the physical properties. Better treatment combination from the experiment I was selected and it has been treated with three silica types (Powder silica, Hi-sil 243 and New-sil 155). Physical properties such as: tensile strength, tearing, abrasion resistance, 300 % modulus, elongation at break, hardness and rebound resilience and cure characteristics were measured in both experiments. Four replicates were used for each test. Data was analyzed with one way ANOVA using Minitab 16 statistical software and mean comparison was done using Tukey test. Results and Discussion According to the previous studies it shows that the increasing silica loading tends to increase in the cure time (t90) and scorch time (ts2) of the rubber vulcanizates (Okel and Waddell, 1994). These properties have increased with increasing silica. At 15 phr level of silica, it tends to reduce the scorch protection. This can be due to the insufficient coupling of silane with silica during compounding. Higher processing safety obtained as silica loading high due to formation of