Browsing by Author "Edirisinghe, E.D.S."

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    The Effect of Bis-(3-triethoxysilylpropyl)-Tetrasulfane and Polyethylene Glycol on the Properties of Natural Rubber/ Mica Composites
    (Uva Wellassa University of Sri Lanka, 2021) Edirisinghe, E.D.S.; Somarathna, Y.R.; Withanage, N.S.; Dhanukamalee, H.M.H.; Samarasinghe, I.H.K.; Siriwardena, S.
    The bis-(3-triethoxysilylpropyl)-tetrasulfane (Si69) is widely applied as a coupling agent to rubber- filler interactions in silica filled rubber composites. In this study, the effect of bis-(3- triethoxysilylpropyl)-tetrasulfane (Si69) and polyethylene glycol (PEG) on the properties of natural rubber (NR)/mica composites has been studied. The mica loading and the total weigh of Si69/PEG were kept constant at 30 phr and 2 phr, respectively. A composite free from Si69/PEG (SP00) was used as the control, while ratios of the above chemicals (Si69: PEG) were varied as 1:0, 0:1 and 1:1 in the other composites. These three systems were denoted SP10, SP01 and SP11, respectively. Curing characteristics, physico-mechanical properties and thermal degradation of NR/mica composites were investigated. The maximum cure time (Tc90) and scorch time (TS2) were exhibited in the SP10 compound. However, introduction of PEG into the system with Si69 in SP11 composite yield a reduction in Tc90 and TS2, which were comparable with the control (SP00). Maximum tensile strength and elongation at break were observed in Si69 treated NR/mica composite (SP10). This could be attributed to the improved rubber-filler interactions caused by incorporation of higher amounts of Si69 (2 phr). Further, the composite treated with both Si69 and PEG (SP11) with 1 phr each, has shown the second highest tensile strength among candidate composites. However, the enhanced moduli values at 100%, 300% and 500% elongation indicated better rubber-filler interactions in SP11 composite than SP10. The same reason may have resulted the highest hardness and resilience values in SP11 composite. The thermogravimetric analysis indicated that the application of Si69 and/or PEG have no significant impact on the thermal degradability of NR/mica composites. It was also found that SP01 exhibited the highest swelling ratio among all samples. Therefore, overall results indicated that PEG/Si69 treated system (SP11) could be employed more effectively than individual use of Si69 and PEG to optimize the cure characteristics, while improving the physico-mechancial properties of NR/mica composites. Keywords: Mica; Natural rubber composites; Polyethylene glycol; Coupling agent; Rubber-filler interactions
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    Effect of Bis-(3-Triethoxyslylpropyl)- Tetrasulfide and Polyethylene Glycol on the Properties of Natural Rubber/ Mica Composite
    (Uva Wellassa University of Sri Lanka, 2016) Edirisinghe, E.D.S.
    The bis-(3-triethoxysilylpropyl)-tetrasulfane (Si69) is widely applied as a coupling agent to rubber-filler interactions in silica filled rubber composites. In this study, the effect of bis-(3-triethoxysilylpropyl)-tetrasulfane (Si69) and polyethylene glycol (PEG) on the properties of natural rubber (NR)/mica composites has been studied. Mica is one of the widely available silica-containing minerals in Sri Lanka. The effect of Si69 and PEG on the properties of natural rubber (NR)/mica composites have been observed while keeping the mica loading constant (30 phr). By keeping the total weight of Si69/PEG at 2 phr, the ratios of the Si69: PEG were changed as 0:1 (SP01), 1:0 (SP10), and 1:1 (SP11). The composite free from Si69/PEG (SPOO) was considered as the control. SP10 recorded the highest cure time (Tao) and scorch time (T52). The introduction of PEG has reduced cure time (Tao) and scorch time (T52) in SPO1 and SP11, which are comparable with the control. Higher tensile strength emphasized better rubber-filler interactions in the composites with Si69 (SP10 and SP11). Although, SP10 recorded the highest elongation at break, SP11 resulted the enhanced moduli,. at 100%, 300%, and 500% elongation, showing better rubber-filler interactions than SP10. This further supports the hardness and resilience data, of which SP 11 yielded the highest hardness and resilience values. Thermal aging results showed enhanced tensile strengths in SPOO and SP10, which may be attributed to the formation of more crosslinks. PEG could increase the viscosity of rubber causing permanent heat deformation, thus resulting inferior tensile aging results in the SPO1 and SP11. The thermogravimetric analysis revealed that Si69 and PEG have no significant effect on the degradation of composites. The highest swelling ratio was exhibited by SP01. Overall results specified that the use of Si69 with PEG may be more effective and have optimized overall properties of NR/mica composites. Keywords: Coupling agent, Mica, Natural rubber composites, Polyethylene glycol